
Plastic backing sheets are available in a variety of materials, including polyester, glass fabric, and polyvinyl chloride (PVC). While the pH level of these sheets is not explicitly mentioned, the type of plastic used is a key factor in determining its chemical stability and suitability for different applications. For example, PVC is not recommended for archival photographic or document storage due to its chemical instability and tendency to emit hydrochloric acid as it deteriorates. On the other hand, some plastics, such as the TLC plastic sheets, are specifically designed to be neutral to separate neutral compounds. Fabric-backed sheets, which are engineering plastic sheets bonded with fabric, offer extreme peel strength and are used in applications requiring fiber reinforcement.
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What You'll Learn
- Plastic enclosures manufactured from polyvinyl chloride (PVC) are not recommended for archival use
- PVC emits damaging hydrochloric acid as it deteriorates
- There are other types of plastic that are considered archival safe
- TLC plastic sheets are available in neutral pH levels
- Basic aluminium oxide plates are best for separating basic compounds

Plastic enclosures manufactured from polyvinyl chloride (PVC) are not recommended for archival use
To avoid damage to archival materials, it is recommended to use inert, chemically stable plastics that are considered archival-safe. These plastics do not interact with other materials and are free from volatile plasticizers. In some countries, PVC has been banned from use in children's toys and other products that come into close contact with children due to safety concerns.
When choosing a plastic enclosure for archival purposes, it is important to look for plastics described as "inert" or "stable". These terms indicate that the plastic is suitable for preservation. The thickness of the plastic, measured in mils (one-thousandth of an inch), is also a factor to consider. For oversized or fragile documents and photographs, a higher mil plastic will provide more support and protection.
While PVC is widely used in various applications, including plumbing pipes and photo storage pages, it is not the best choice for archival enclosures. By choosing inert, chemically stable plastics, archivists can ensure the long-term preservation of valuable documents and photographs without the risk of damage caused by unstable plastics like PVC.
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PVC emits damaging hydrochloric acid as it deteriorates
Polyvinyl chloride (PVC) is a versatile material used in various applications, from plumbing in homes to industrial settings. Its inherent chemical resistance makes it a popular choice across multiple sectors. However, it is important to understand its limitations and handle it correctly to ensure maximum performance.
One of the critical aspects of PVC is its chemical compatibility with other substances, especially hydrochloric acid (HCl). While PVC can withstand hydrochloric acid to some extent, the compatibility is not a straightforward "yes" or "no" answer. It depends on several factors, including the concentration and temperature of the acid.
At lower concentrations, such as 20% hydrochloric acid, PVC is deemed to have excellent compatibility. As the concentration increases to 37%, the compatibility is still considered good. However, at 100% concentration, the effect on PVC is severe. Additionally, high temperatures combined with exposure to aggressive chemicals can accelerate the deterioration of PVC pipes.
To ensure the safe use of PVC in chemical plants, it is recommended to provide proper support for PVC piping, use specially formulated solvent cement for leak-free joints, and test PVC under specific exposure conditions. These measures will help maintain the integrity of PVC in such environments.
In conclusion, while PVC can emit damaging hydrochloric acid as it deteriorates, the extent of the damage depends on various factors, including the concentration and temperature of the acid. Proper handling, maintenance, and understanding of its limitations are crucial to minimizing the negative impact of hydrochloric acid emission during PVC deterioration.
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There are other types of plastic that are considered archival safe
While some plastics can be harmful to the objects they are supposed to protect, there are other types of plastic that are considered archival safe. Polypropylene is one such plastic that is often used for storing photographs, papers, and philatelic materials. It is similar to polyester film in clarity and provides a safe alternative to PVC for photo storage. The National Postal Museum, for instance, uses polypropylene page protectors for album pages when rehousing a collection.
Polyester is another type of plastic that is considered archival safe. It is structurally sound and is often used for storing photographs, papers, and other delicate items. Polyester film is known for its clarity and strength, making it a good choice for protective enclosures.
Fabric-backed sheets are also considered archival safe. These are engineering plastic sheets that are backed with a polyester or glass fabric layer during the production process. The fabric incorporates itself into the sheet while it is still hot, resulting in extreme peel strength. Fabric-backed sheets are often used in applications where fiber reinforcement is required, such as in decorative cloths for fancy thermoformed items or orthopedic articles for children.
Overall, it is important to choose the right type of plastic for your specific needs. Some plastics, like PVC, can be damaging to archival materials due to the presence of plasticizers. By choosing archival-safe plastics like polypropylene, polyester, and fabric-backed sheets, you can better protect your photographs, documents, and other valuable items.
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TLC plastic sheets are available in neutral pH levels
Thin Layer Chromatography (TLC) plastic sheets are available in neutral pH levels and are used to perform thin-layer chromatography. These sheets are made of aluminium oxide and are used to analyse basic and neutral compounds at different pH levels. The choice between the two types of aluminium oxide plates depends on the pH range in question. Basic aluminium oxide plates are best for separating basic compounds under aqueous conditions, while neutral plates are ideal for separating neutral compounds.
TLC plastic sheets with aluminium oxide 60 F₂₅₄ are available in packages of 25 sheets, each measuring 20 cm by 20 cm. These sheets have a layer thickness ranging from 170 to 220 µm, with a deviation of ≤ 35 µm per plate. The d 10, d 50, and d 90 values, determined using laser diffraction size distribution, are 3-5 µm, 8-12 µm, and 18-25 µm, respectively.
The TLC aluminium plates are versatile and can handle a wide range of applications due to the presence of neutral and basic aluminium oxides with different pore sizes. The pore sizes of 60 Å and 150 Å allow for the separation of compounds with varying molecular sizes. These sheets are also available with or without a fluorescence indicator, which can be useful for certain types of analyses.
TLC plastic sheets are a valuable tool in analytical chemistry, particularly in the separation and analysis of compounds with different pH levels. The availability of neutral pH sheets expands the range of applications for TLC and allows for the study of compounds that are neither acidic nor basic. This neutral pH option fills an important gap in the market, catering to the needs of professionals who require a reliable method for separating and analysing neutral compounds.
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Basic aluminium oxide plates are best for separating basic compounds
Aluminium oxide plates are used for thin-layer chromatography (TLC) and are ideal for analyzing basic and neutral compounds at different pH levels. The two types of aluminium oxide plates available are basic and neutral. Basic aluminium oxide plates are best suited for separating basic compounds under aqueous conditions, while neutral plates are ideal for separating neutral compounds. These plates are available with or without a fluorescence indicator and can handle a wide variety of applications. The pore sizes of the plates also contribute to their versatility, with neutral and basic aluminum oxides featuring 60 Å and 150 Å pore sizes.
Basic aluminium oxide plates are specifically designed to interact with basic compounds, which have a pH greater than 7. The plate's surface is coated with a layer of aluminium oxide, a basic substance with a high pH. When a sample containing a mixture of compounds is applied to the plate, the basic compounds are attracted to the plate's surface due to their similar pH levels. This attraction causes the basic compounds to move up the plate, separating them from the other compounds in the sample.
The plate's ability to separate compounds is influenced by the pH and the presence of aqueous conditions. Under aqueous conditions, the basic compounds are more soluble and mobile, allowing them to travel further up the plate. Additionally, the basic nature of the plate enhances the separation by creating a more favourable environment for the basic compounds to move away from the neutral or acidic compounds in the sample.
The layer thickness of basic aluminium oxide plates also plays a role in their effectiveness. A typical plate has a layer thickness ranging from 210 to 270 µm, with minimal deviation. This consistent layer thickness ensures that the compounds experience a uniform environment as they move up the plate, promoting effective separation. The plates are also designed with specific hRf-values, such as brucine, papaverine, and alkaloid test ranges, to further enhance the accuracy of compound identification.
In summary, basic aluminium oxide plates are the best choice for separating basic compounds due to their compatibility with aqueous conditions and their ability to create a favourable environment for the movement of basic compounds. The plate's surface properties, pH, and layer thickness all contribute to its effectiveness in separating and analyzing basic compounds.
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Frequently asked questions
Plastic backing sheets are engineering plastic sheets that are backed with a polyester or glass fabric layer on one side during the production process.
It depends on the type of plastic. Plastic enclosures manufactured from polyvinyl chloride (PVC) are not recommended for archival photographic or document storage as they are not chemically stable and can emit damaging hydrochloric acid as they deteriorate. However, there are other types of plastic enclosures that are chemically stable and considered archival safe. Additionally, TLC plastic sheets are explicitly marketed as being neutral.
Plastic backing sheets are used in various applications, primarily where fiber reinforcement is required, and the sheet acts as a liner. They are also used for decorative cloths for fancy thermoformed items or orthopedic articles for children.











































