
White plastic items like old video game consoles, storage boxes, and packing tape are known to turn yellow over time. This phenomenon is attributed to increased exposure to UV light, causing a chemical reaction in the polymer backbone, resulting in the formation of molecules that act as dyes. While UV light is the primary culprit, other factors like visible light, extreme temperatures, humidity, and solvents can also contribute to the discolouration. Understanding the degradation process of polymers is essential for developing alternative plastic products that resist yellowing and have a longer lifespan.
| Characteristics | Values |
|---|---|
| Reason for white plastic turning yellow | Excess exposure to UV light |
| Other reasons | Extreme temperatures, humidity, visible light, solvents |
| Impact | Initiates and accelerates the chemical reaction of the polymer |
| Solution | Use an UV-resistant topcoat |
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What You'll Learn

UV light exposure
The discolouration of white plastic items is a common phenomenon, and it is mostly due to excess UV light exposure. The sun emits UV rays, and over time, the exposure to these rays causes the plastic to change colour. The process is similar to how humans get sunburnt.
The change in colour does not happen immediately, but the increase in UV light exposure initiates and accelerates a chemical reaction in the plastic's polymer structure, which eventually turns it yellow. This process is known as photodegradation, where the UV radiation breaks down the chemical bonds in the dyes. The dye's chemical structure reflects certain wavelengths of light, and when this structure is destroyed, it no longer reflects light the same way, resulting in a colour change.
The impact of UV light exposure on plastics is not limited to colour change. The photodegradation process also affects the plastic's structural integrity, making it more brittle. This can have safety implications, especially for items like PVC pipes and ropes that support weight.
To prevent or delay the yellowing of plastics, UV-resistant coatings can be applied. Additionally, storing plastic items away from direct sunlight and other sources of UV light can help reduce their exposure and slow down the discolouration process.
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Extreme temperatures
However, it is not just high temperatures that can cause plastic to yellow. Low temperatures can also be a factor, as well as other environmental conditions such as humidity, exposure to solvents, and visible light.
The combination of these factors can cause damage to the polymer, eventually leading to its failure. The damage caused by extreme temperatures can be mitigated through the use of light stabilizers, such as UV-absorbing stabilizers, quenchers, or HALS. These additives can trap free radicals formed by exposure to UV radiation and prevent them from causing damage.
Additionally, proper care and maintenance of plastic materials can help prevent yellowing caused by extreme temperatures. This includes avoiding exposure to high temperatures, proper cleaning with mild detergents and soft cloths, and regular maintenance to monitor for signs of discolouration or other damage.
By understanding how polymers react to extreme temperatures and other environmental factors, scientists can develop new polymers or alternative materials that are more resistant to yellowing and have longer lifespans.
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Humidity
While UV light exposure is the most common cause of white plastic turning yellow, other factors such as humidity, extreme temperatures, and exposure to solvents can also contribute to this discoloration.
In humid environments, such as Hawaii, Florida, and Illinois, people have observed yellowing of white plastic items, including ceiling flood lights, electrical outlets, and window air conditioners. The humidity in these locations is believed to be a significant factor in the discoloration of plastic.
Additionally, high humidity can promote the growth of mold, mildew, or bacteria on plastic surfaces, which can contribute to discoloration. In some cases, the presence of these microorganisms can also break down the plastic material, making it more susceptible to degradation and subsequent yellowing.
To mitigate the effects of humidity on white plastic, it is essential to maintain a controlled environment with stable temperature and moisture levels. Storing plastic items in cool, dry places can help slow down the yellowing process. Additionally, regular cleaning and maintenance of plastic surfaces can remove any mold or mildew buildup, preventing discoloration and extending the lifespan of the material.
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Visible light
Plastics, such as polyethylene, commonly used in various products, are susceptible to colour change due to their chemical composition. The backbone of the polymeric structure of polyethylene undergoes changes when exposed to UV light, leading to the formation of new chiral nanostructures on its surface. These nanostructures interact with visible light, causing the plastic to appear yellow.
The process is not instantaneous, and the colour change occurs gradually. The more exposed plastic is to visible light, the quicker its colour will change. This is because the light initiates and accelerates a chemical reaction in the polymer, eventually turning it yellow.
Other factors, such as extreme temperatures, humidity, and solvents, can also contribute to plastic degradation. However, visible light exposure remains a significant factor in the yellowing process.
To prevent or slow down the yellowing of plastics, it is essential to minimise their exposure to direct sunlight and artificial light sources. Additionally, using UV-resistant coatings or treatments can help protect plastics from the detrimental effects of visible light.
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Solvents
Exposure to solvents can cause plastics to turn yellow. However, UV light exposure is the most common cause of yellowing in plastics. The more exposed plastic is to UV light, the quicker it changes colour. The change in colour does not happen immediately but takes time. Increased exposure to UV light initiates and accelerates the chemical reaction of the polymer, which eventually turns the plastic into a yellow colour.
Other factors that can cause plastics to turn yellow include increased exposure to visible light, extreme temperatures, and humidity. Additionally, the quality of the plastic mixture can play a role, with lower-quality plastics being more prone to yellowing.
To prevent yellowing, it is recommended to use a UV-resistant topcoat or add UV-absorbing stabilizers, quenchers, or HALS during the manufacturing process to trap free radicals formed by UV exposure and prevent damage.
There are several methods to remove yellowing from white plastic:
- Soaking the plastic in hydrogen peroxide for 3-4 hours to remove discolouration and stains. This method is especially effective on plastics that have turned entirely yellow.
- Using the Retrobrite process, which involves soaking the plastic in 12% hydrogen peroxide and exposing it to UV LED light strips.
- Soaking the plastic in bleach for 1-2 hours to remove stubborn yellow stains. It is important to test the bleach on a small section of the plastic first and to take safety precautions when handling bleach.
- Submerging the plastic in vinegar for 2-3 hours. White vinegar is a safe alternative to harsh cleaners and is effective in removing yellowing from plastic.
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Frequently asked questions
Yes, all white plastic will eventually turn yellow, although the process is accelerated by exposure to UV light, extreme temperatures, and humidity.
The yellowing of white plastic is caused by the formation of molecules that act as dyes. Specifically, it is due to the creation of chiral chemical structures on the surfaces of the plastic during exposure to UV light.
To prevent white plastic from turning yellow, you can use a UV-resistant topcoat or store the plastic items in a dark, temperature-controlled environment.
You can try using a peroxide-based product, such as hair bleach, to restore yellowed white plastic. Simply apply the product to the plastic, seal it in a plastic bag, and leave it in a warm place for a few days.
The rate at which plastic turns yellow is influenced by its exposure to UV light, extreme temperatures, and humidity. Environments with high levels of UV light, such as sunny regions or places with minimal shade, will cause plastic to turn yellow faster. Similarly, environments with extreme temperatures or high humidity can accelerate the yellowing process.








































