
Water absorption is a critical property in the plastics industry, as it indicates how much moisture a plastic material will absorb over time. This property is measured using the ASTM D570 and ISO 62 standards, which involve immersing a plastic specimen in distilled water for 24 hours at a specified temperature. While most polymers have a natural tendency to absorb water, the absorption rate varies depending on the material. For example, HDPE has very low water absorption, while nylon has a higher rate of moisture absorption. The presence of moisture in the polymer structure can impact the material's strength, dimensional stability, and electrical insulation characteristics. Additionally, absorbed moisture can act as a plasticizer, reducing the glass transition temperature of the plastic. Therefore, understanding the water absorption properties of plastics is crucial for selecting appropriate materials for specific environments and ensuring product reliability.
| Characteristics | Values |
|---|---|
| Water absorption capacity | High water absorption can lead to swelling, warping, reduced strength, and compromised performance. |
| Impact on performance | Dimensional stability, mechanical properties, electrical insulation characteristics, thermal insulation, and dielectric properties are all affected. |
| Types of plastics | Polyolefins such as PE, PP, and polybutylene absorb little water and are unaffected by aging in water. |
| Testing standards | ASTM D570 and ISO 62 are widely used standards to measure water absorption in plastics. |
| Testing procedures | Specimens are dried, cooled, weighed, immersed in water at specified temperatures, and then re-weighed to determine the percentage of weight gain due to water absorption. |
| Expression of results | Water absorption is expressed as an increase in weight percent or % weight gain of a plastic specimen. |
| Impact on polymer structure | Absorbed water can lead to irreversible degradation of the polymer structure. |
| Applications | Water absorption properties are considered in the design and material selection for medical, construction, and other applications. |
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What You'll Learn

Plastic cover material
Plastic is a versatile material used in a wide range of applications, from food packaging to industrial components. While plastics are commonly associated with water resistance, not all plastics are created equal when it comes to their ability to absorb water. Some plastic compounds are specifically chosen for their low water absorption properties, making them ideal for applications where moisture resistance is crucial.
One example of a plastic with low water absorption is High-Density Polyethylene (HDPE). HDPE is often used in food packaging and is known for its ability to resist moisture absorption. This makes it suitable for storing food items and other products that need to be kept dry. However, as one Reddit user points out, the level of water absorption can depend on factors such as the thickness of the material, the surface area exposed, and the duration of exposure.
In addition to HDPE, other plastics with low water absorption properties include polyethylene (UHMW), acetal, polypropylene, and polytetrafluoroethylene (PTFE), commonly known as Teflon. These plastics are often selected for applications where maintaining dimensional stability and electrical insulation properties is critical, such as in electronic components or mechanical parts.
The water absorption rate of plastics can significantly affect their performance. For instance, in high-humidity environments or underwater applications, plastics with low water absorption rates are preferred to prevent dimensional changes and maintain their structural integrity. On the other hand, some plastics with higher water absorption rates may be chosen for specific purposes, such as controlling the rate of drug delivery in the medical field.
When selecting plastic materials for a particular application, it is essential to consider the environment in which the plastic will be used and the potential impact of water absorption on its performance. By choosing the right type of plastic with the appropriate water absorption properties, manufacturers can ensure the effectiveness and longevity of their products.
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Water absorption vs penetration
In the context of skincare, "penetration" and "absorption" are often used interchangeably but refer to different processes. Skin penetration occurs when skincare ingredients pass through the epidermis (the outer layer of the skin) and reach the dermis, where collagen and elastin fibres reside. On the other hand, absorption refers to the process by which these ingredients are not only penetrating the skin but are also taken up by the body's circulatory system.
Lipid-soluble (oil-soluble) ingredients tend to penetrate the skin more easily than water-soluble ones because the skin's natural barrier is composed of lipids and dead skin cells. Certain ingredients are designed to enhance penetration by disrupting the lipid structure of the stratum corneum. The effectiveness of a product's penetration can significantly influence its overall efficacy. For example, ingredients like hyaluronic acid and glycerin are designed to penetrate the upper layers of the skin and provide hydration without being absorbed into the bloodstream.
The rate and extent of absorption depend on several factors, including the molecular size and solubility of the substance, as well as the condition of the skin. For instance, damaged or compromised skin can lead to increased absorption. Similarly, the penetration depth of a substance can vary with its material type, microstructure properties, and temperature. For example, water at 25.1°C can absorb up to 14 mm of microwaves at 2.45 GHz, while its penetration depth increases to 57 mm at the same frequency when the temperature rises to 90.1°C.
While some plastics may have low water absorption properties, such as HDPE, they may still absorb water given certain conditions, such as increased surface area, duration of exposure, and thickness of the material. However, water absorption does not necessarily imply that water can penetrate the plastic. For example, some plastic toys that contain liquids may lose water volume over time, indicating that water absorption and penetration behaviours can vary across different types of plastics and conditions.
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Plastic degradation
The effects of heat, light, air, and water are significant factors in the degradation of plastic polymers. Oxidation and chain scission cause major chemical changes, reducing the molecular weight and degree of polymerization. These changes affect physical properties like strength, malleability, and appearance. Additionally, plastic additives and plasticizers can impact biodegradation, and some additives can improve biodegradability.
Mechanical degradation occurs due to friction and can be reduced by adding lubricants or processing aids. Recycled plastics, such as those produced by simple re-melting, often display more degradation and may have poorer properties. Technologies have been developed to both inhibit and promote degradation, such as using polymer stabilizers to extend the lifespan of plastic items.
Biodegradable plastics have functional groups or enzyme-sensitive linkages that can be broken down by enzymatic, photo-, and thermo-oxidation processes. However, high polymers are more challenging to disintegrate due to their short chains and low molecular weights. The efficiency of microbial degradation needs improvement, and there is a need to find more suitable strains for plastic degradation.
In summary, plastic degradation is a complex process influenced by various factors, and it is essential to address this issue to mitigate the environmental and health impacts of plastic pollution.
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Plastic testing standards
ASTM Standards
ASTM International, originally known as the American Society for Testing and Materials, develops technical standards for a variety of industries, including plastics. ASTM standards provide specific test methods, practices, and guides for evaluating plastic materials. For example:
- D5226-21: Standard Practice for Dissolving Polymer Materials
- D3465-21: Standard Guide for Purity of Monomeric Plasticizers by Gas Chromatography
- D6980-17: Standard Test Method for Determination of Moisture in Plastics by Loss in Weight
- D7191-24: Standard Test Method for Determination of Moisture in Plastics by Relative Humidity Sensor
ISO Standards
The International Organization for Standardization (ISO) also plays a crucial role in establishing standards for plastics testing. ISO standards provide frameworks for characterizing molding materials and other plastic products:
- ISO 10350: Single-point data for molding materials
- ISO 11403: Multipoint data for molding materials
- ISO 17282: Design data for molding materials
Other National and International Standards
In addition to ASTM and ISO standards, there are various national and international standards committees that contribute to the development of plastic testing standards. ZwickRoell, for instance, actively participates in these committees, gaining access to important information and discussions. This collaborative effort ensures the reliability and consistency of plastic testing across different regions.
Specific Tests
- Ash Content in Plastics (D5630-22)
- Measurement of Fines and Dust Particles on Plastic Pellets by Wet Analysis (D7486-22)
- Determination of Low-Level Phthalates in Poly(Vinyl Chloride) Plastics by Solvent Extraction-Gas Chromatography/Mass Spectrometry (D8133-23)
- Shear Tests and Compression Tests for Railroad Ties (FFU)
These plastic testing standards enable consistent evaluation, ensuring the safety and quality of plastic products across different industries.
Regarding your query about why a plastic cover did not absorb water, it's important to understand that plastic's ability to absorb water varies depending on the material and its properties. While some plastics have low water absorption rates, others may absorb moisture over time. The behaviour of a specific plastic cover depends on factors such as material type, thickness, surface area, and duration of exposure.
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Humidity and moisture
The absorption of water by plastics is influenced by various factors, including the type of plastic, humidity, and moisture content. While some plastics are designed to resist water absorption, others are hygroscopic, meaning they attract and absorb moisture due to their chemical characteristics. This hygroscopic nature can be beneficial or detrimental depending on the application. For example, in the context of a plastic bag, the relative humidity in the packaging area and the enclosed air's moisture content are crucial. If the sealed bag contains goods with moisture, the water vapour may condense within the bag, potentially damaging its contents. This is why products like fresh fruits are packaged in perforated plastic containers to prevent moisture buildup.
Hygroscopic plastics, such as polyamides, form hydrogen bonds in the presence of moisture. While this can be undesirable during processing, it becomes necessary afterward to prevent the plastic pieces from becoming brittle. On the other hand, non-hygroscopic polymers like PP and PE are less susceptible to moisture absorption, although surface moisture can still influence staining.
The moisture absorption of plastics can impact their processing and properties. For instance, absorbed moisture can act as a plasticizer, reducing the glass transition temperature and strength of the plastic. Additionally, excessive moisture absorption can lead to irreversible degradation of the polymer structure. This is particularly important for precision-machined parts, where even a small percentage of moisture absorption can cause the part to exceed tolerance and become unusable.
To mitigate the effects of moisture, products can be packaged with desiccant pouches or vacuum-sealed in moisture-impermeable layers. These methods help prevent moisture uptake in humid environments and maintain the integrity of the packaged goods.
Overall, while plastics may not completely absorb water, they can be susceptible to moisture absorption, especially in humid environments. The extent of absorption depends on the specific type of plastic and the environmental conditions it is exposed to. Proper packaging and moisture control are essential to preventing potential damage caused by water absorption in plastics.
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Frequently asked questions
The plastic cover likely did absorb some water, as most polymers have a natural tendency to absorb water. However, the amount of water absorbed depends on the type of plastic and the duration of exposure. Some plastics, like HDPE, have very low water absorption rates.
Yes, the type of plastic does affect water absorption. For example, polymers such as Nylon (PA) have a higher rate of moisture absorption than others. On the other hand, polyolefins like PE, PP, and polybutylene absorb little water.
Water absorption can lead to swelling, warping, reduced strength, and compromised performance in plastic products. It can also affect electrical insulation characteristics and dimensional stability. Additionally, absorbed water can cause irreversible degradation of the polymer structure over time.
Water absorption in plastics is typically measured using the ASTM D570 and ISO 62 standards. This involves drying and weighing plastic specimens, then immersing them in water at controlled temperatures for 24 hours or until equilibrium is reached. The percentage of water absorbed is calculated based on the weight gain of the specimens.











































